CAS 106-99-0 · IECSC · People's Republic of China

1,3-Butadiene under IECSC

C4H6 · 1,3-丁二烯

Status: Listed. 1,3-Butadiene is on the IECSC public portion as a foundational steam-cracker C4 product. New-substance notification under MEE Decree No. 7 (2010) is NOT required. **1,3-Butadiene IS on China's Catalog of Hazardous Chemicals** (Carc 1A + Muta 1B + Flam. Gas 1A + Press. Gas classification matching EU REACH harmonised). Hazardous Chemicals Operation Permit IS required for production / storage / distribution. NOT on Highly Toxic Chemicals Catalog (lighter than benzene batch 22 + phenol batch 13 + formaldehyde batch 18 + aniline batch 26; butadiene is gaseous and not on Highly Toxic Catalog despite Carc 1A). NOT on Easily-Made Drugs Precursor Chemicals Catalog. **0% China VAT export rebate** for butadiene (HS 290124) reflects Beijing aromatic-petrochemical export-discouragement signal. China dominates global capacity (~30%, ~5-6 Mt/yr).

1,3-Butadiene is comfortably IECSC-listed but IS on Catalog of Hazardous Chemicals (Hazardous Chemicals Operation Permit chain required). NOT on Highly Toxic Chemicals Catalog (lighter than benzene batch 22 + phenol batch 13 + formaldehyde batch 18 + aniline batch 26; butadiene is gaseous so not on Highly Toxic Catalog despite Carc 1A). NOT on Easily-Made Drugs Catalog. **0% China VAT export rebate** is structural Beijing aromatic-petrochemical export-discouragement signal. China dominates global capacity (~30%, ~5-6 Mt/yr) led by Sinopec (Yangzi + Shanghai + Maoming + Yueyang), CNPC (Daqing + Karamay), Hengli Petrochemical Dalian, Wanhua Chemical Yantai, Zhejiang Petrochemical Zhoushan / ZRCC. Production: steam-cracker C4 fraction extraction (~95% globally). **Steam-cracker capacity additions drive coupled butadiene supply growth**: Chinese steam-cracker capacity additions 2024-2026 extend Chinese butadiene supply growth. Press. Gas + Flam. Gas 1A drives refrigerated liquefied or compressed gas storage + ATEX-zoned warehousing overhead.

Listing and threshold

Substance 1,3-Butadiene (CAS 106-99-0), C4H6
Regime China Inventory of Existing Chemical Substances (IECSC), administered by the Ministry of Ecology and Environment (MEE)
Jurisdiction People's Republic of China
Status Listed
Tonnage threshold No new-substance threshold applies. Hazardous Chemicals Operation Permit required regardless of volume

Classifications under this regime

  • Listed in China's Catalog of Hazardous Chemicals
  • NOT on China's Highly Toxic Chemicals Catalog
  • NOT on the Easily-Made Drugs Precursor Chemicals Catalog
  • GB/T 7717-2008 specification applies for industrial-grade 1,3-butadiene (Chinese national standard)
  • GB/T 7717-2008 covers minimum 99.5% purity (industrial-grade), water content, dimer content, oxygen content, TBC inhibitor specification
  • GACC export classification: HS 290124 (1,3-butadiene)
  • China dominates global capacity (~30%, ~5-6 Mt/yr); ~95% via steam-cracker C4 fraction extraction (oxidative dehydrogenation route at Sinopec Yueyang + smaller scale)
  • GB 6944-2012 dangerous-goods transport classification: Class 2.1 (flammable gas), UN 1010 (refrigerated liquefied or compressed)

Restrictions and conditions of use

  • **Hazardous Chemicals Operation Permit IS required** for any party producing, storing, or distributing 1,3-butadiene
  • Hazardous Chemicals Road Transport Permit required for road shipment of bulk 1,3-butadiene
  • Customs Inspection Order may apply for export consignments
  • No specific export-restriction or quota system applies
  • **0% China VAT export rebate** for 1,3-butadiene (HS 290124); reflects Beijing aromatic-petrochemical export-discouragement signal
  • GB/T 17519 Chinese-language SDS required for domestic distribution
  • MEE 2024 guidance: butadiene is steam-cracker C4 by-product so capacity is determined by steam-cracker C2 / C3 / C4 economics structurally

Importer obligations

For Chinese-origin 1,3-butadiene exported abroad, no IECSC obligation falls on the foreign importer. The export-side documentation pack focuses on the Hazardous Chemicals Operation Permit chain, the GB/T 17519 Chinese-language SDS, and ADG 7.7 Class 2.1 transport documentation (refrigerated liquefied or compressed gas). Major Chinese producers (Sinopec Yangzi + Sinopec Shanghai + Sinopec Maoming + Sinopec Yueyang, CNPC Daqing + CNPC Karamay, Hengli Petrochemical Dalian, Wanhua Chemical Yantai, Zhejiang Petrochemical Zhoushan / ZRCC) compete with EU producers (BASF Ludwigshafen, Shell Chemicals Pernis + Wesseling, INEOS Köln, ExxonMobil Antwerp), US producers (TPC Group, LyondellBasell, ExxonMobil), Korean producers (Kumho Petrochemical Yeosu, LG Chem Yeosu, Lotte Chemical Yeosu, S-Oil Onsan).

Required documents

  • GACC export declaration with HS code 290124
  • Industrial-grade certificate per GB/T 7717-2008 (minimum 99.5% purity)
  • GHS-compliant SDS in Simplified Chinese per GB/T 17519-2013 (effective 31 January 2014, references UN GHS 4th revised edition; verify against the current version of GB/T 17519 at https://www.codeofchina.com/standard/GBT17519-2013.html)
  • Hazardous Chemicals Operation Permit chain documentation (producer / forwarder / port operator)
  • Hazardous Chemicals Road Transport Permit (where road-shipped from inland producers)
  • GB 6944-2012 Class 2.1 dangerous-goods transport documentation (refrigerated liquefied or compressed gas)

Common compliance traps

The pitfalls that have bitten importers on this lane in the past. None of these is theoretical.

  • Hazardous Chemicals Operation Permit chain is the dominant operational complexity
  • **0% China VAT export rebate** is structural Beijing aromatic-petrochemical export-discouragement signal
  • NOT on Highly Toxic Chemicals Catalog (lighter than benzene batch 22 + phenol batch 13 + formaldehyde batch 18 + aniline batch 26)
  • NOT on Easily-Made Drugs Catalog
  • Major Chinese producers concentrated at coastal Sinopec + CNPC + Hengli + Wanhua + Zhejiang Petrochemical / ZRCC mega-complexes
  • Production route: steam-cracker C4 fraction extraction (~95% globally); ~30-40% of C4 fraction is butadiene
  • **Steam-cracker capacity additions drive coupled butadiene supply growth**; Chinese steam-cracker capacity additions 2024-2026 (Hengli Petrochemical Phase 4, Zhejiang Petrochemical Phase 3, Wanhua Chemical Yantai expansion) extend Chinese butadiene supply growth
  • TBC (4-tert-butylcatechol) inhibitor is critical for safe storage and transport (prevents thermal-runaway dimerisation); typical 50-150 ppm spec
  • Press. Gas + Flam. Gas 1A drives refrigerated liquefied or compressed gas storage + ATEX-zoned warehousing overhead

Where to read next

For substance-level identifiers (formula, molecular weight, SMILES, InChIKey), GHS hazard profile, IMDG transport class, and full sourcing reference for 1,3-butadiene, see the CAS 106-99-0 sourcing reference.

For grade-by-grade buying notes, freight maths, supplier-tier pricing, and a worked landed-cost example, the 1,3-butadiene cornerstone hub covers the full sourcing chain.

For the structure and history of IECSC, see the IECSC glossary entry.

Need cross-jurisdiction compliance support on this substance? Run it through the REACH / TSCA / IECSC / AICIS / K-REACH checker, or send us the substance and the destination and we will quote FOB China and CIF / DDP landed including the regulatory work on the destination side.

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Free PDF: the same MSDS verification template the Sourzi team uses to cross-reference factory documents against TSCA, REACH, AICIS, and CDR before booking.