CAS 7704-34-9 · REACH · European Union

Sulfur (elemental) under REACH

S8 · 硫磺

Status: Registered. Sulfur is fully registered under REACH at the highest tonnage band (>1,000,000 tonnes/year). **Distinguishing pattern: Production via Claus process at refineries and sour-gas plants (recovered sulfur from H2S in petroleum refining + natural-gas sweetening + tar-sands upgrading) accounting for the dominant share of global production (verify Claus-process share against ICIS or USGS Mineral Commodity Summaries before quoting); minimal residual Frasch-mining production + completes sulfur chain upstream of sulfuric acid batch 2 plus ammonium sulfate batch 31 plus diammonium phosphate batch 30 plus sodium hypochlorite batch 65 (S → SO2 → SO3 → H2SO4 contact-process Haber-equivalent for sulfuric chain) + sulfuric-acid feedstock primary use (~60% of global sulfur consumption, verify against ICIS) plus phosphate-fertiliser sulfuric-acid input plus rubber vulcanisation plus fungicide / pesticide active plus pharma plus pyrotechnic plus battery (Li-S developmental) downstream chains + low-to-moderate hazard profile (Flam. Sol. 2 at fine-powder grade per harmonised CLP entry; verify exact harmonised classification against ECHA Annex VI to CLP Table 3.1 before relying).** No harmonised CLP entry for solid block / lump sulfur; ECHA C&L Inventory aggregates notifier classifications: Flam. Sol. 2 at fine-powder grade only (verify against ECHA https://echa.europa.eu/information-on-chemicals before relying). NOT SVHC. NOT Annex XIV. NO active EU AD case on Chinese-origin sulfur currently (verify against EUR-Lex https://eur-lex.europa.eu/ before invoicing); however, **note that China is structurally net-IMPORTER of sulfur (~30% of global sulfur trade flows into China for sulfuric-acid + phosphate-fertiliser captive consumption, verify against ICIS or S&P before quoting); EU sulfur trade flows are not the dominant story**.

Sulfur is fully REACH-registered with **low-to-moderate hazard profile** (Flam. Sol. 2 at fine-powder grade; solid block / lump typically unregulated). NOT SVHC, NOT Annex XIV. NO active EU AD. **Production: Claus-process at refineries and sour-gas plants dominant** (recovered sulfur from H2S). **Closes sulfur chain upstream of H2SO4 + AS + DAP + NaOCl**. **China is structurally net-IMPORTER of sulfur** (~30% of global trade flows into China). Sulfuric-acid feedstock (~60%) + phosphate-fertiliser + rubber vulcanisation + fungicide / pesticide + pharma + pyrotechnic + Li-S battery downstream chains. EU PPP + BPR + Ph. Eur. monograph framework.

Listing and threshold

Substance Sulfur (elemental) (CAS 7704-34-9), S8
Regime EU Regulation (EC) No 1907/2006: Registration, Evaluation, Authorisation and Restriction of Chemicals
Jurisdiction European Union (EU-27 plus EEA: Iceland, Liechtenstein, Norway)
Status Registered
Tonnage threshold Registration required for any importer or manufacturer placing >1 t/year on the EU market

Classifications under this regime

  • Flam. Sol. 2 at fine-powder grade per harmonised CLP entry: H228 (verify against ECHA Annex VI to CLP Table 3.1 before relying; solid block / lump sulfur is typically unregulated)
  • GHS pictograms: GHS02 (flame) at fine-powder grade
  • IARC: Not classified
  • NOT subject to Drug Precursors or Explosives Precursors scheduling
  • ADR / RID: UN 1350 Class 4.1 PG III (flammable solid) at fine-powder grade; solid block / lump typically unregulated (verify against ADR before relying)
  • **EU Regulation (EC) No 1107/2009 plant-protection-products (PPP)** approval for elemental sulfur as a PPP active substance / fungicide (verify current approval status against https://ec.europa.eu/food/plant/pesticides/eu-pesticides-database/ before relying)
  • **EU Regulation (EU) No 528/2012 biocidal products (BPR)** evaluation for sulfur as biocidal active (verify against ECHA BPR database before relying)
  • **EU Pharmacopoeia monograph** for pharma-grade sulfur (verify monograph reference against EDQM / Ph. Eur. before relying)

Restrictions and conditions of use

  • NOT on REACH Annex XIV (verify against ECHA https://echa.europa.eu/authorisation-list)
  • NOT classified as SVHC (verify against ECHA https://echa.europa.eu/candidate-list-table)
  • NOT subject to any Annex XVII restriction
  • NO active EU AD case on Chinese-origin sulfur currently (verify against EUR-Lex https://eur-lex.europa.eu/ before invoicing)
  • NOT in CBAM Phase 1 scope

Importer obligations

A non-EU producer cannot register directly under REACH. The EU importer of record must hold a registration or rely on an Only Representative (OR). **Note that China is structurally net-IMPORTER of sulfur** (~30% of global sulfur trade flows into China for sulfuric-acid + phosphate-fertiliser captive consumption; verify against ICIS or S&P before quoting); merchant Chinese-origin sulfur exports to the EU are uncommon. Major Chinese sulfur sources are refinery / gas-plant captive Claus-process recovery at Sinopec + CNPC + CNOOC; verify each producer-site pair against the producer's public website before relying on a specific plant.

Required documents

  • REACH registration number on EU side
  • SDS (Flam. Sol. 2 at fine-powder grade)
  • Customs entry HS code 250300 (sulfur, sublimed or precipitated; not chemically pure)
  • ADR documentation for UN 1350 Class 4.1 PG III at fine-powder grade
  • PPP / BPR documentation where placed as fungicide / biocide
  • Pharma-grade Ph. Eur. certification where applicable

Common compliance traps

The pitfalls that have bitten importers on this lane in the past. None of these is theoretical.

  • **Production: Claus-process at refineries and sour-gas plants dominant globally (recovered sulfur from H2S in petroleum refining + natural-gas sweetening + tar-sands upgrading)**
  • **Closes sulfur chain upstream of H2SO4 batch 2 + AS batch 31 + DAP batch 30 + NaOCl batch 65** (S → SO2 → SO3 → H2SO4)
  • NOT SVHC, NOT Annex XIV, NO active EU AD
  • **Sulfuric-acid feedstock ~60% of consumption + phosphate-fertiliser sulfuric-acid input + rubber vulcanisation + fungicide / pesticide active + pharma + pyrotechnic + Li-S battery developmental downstream chains**
  • **China is structurally net-IMPORTER of sulfur (~30% of global trade flows into China)**; merchant Chinese-origin exports rare
  • Major Chinese sources (Claus-process captive): Sinopec + CNPC + CNOOC refinery + sour-gas plants

Where to read next

For substance-level identifiers (formula, molecular weight, SMILES, InChIKey), GHS hazard profile, IMDG transport class, and full sourcing reference for sulfur (elemental), see the CAS 7704-34-9 sourcing reference.

For grade-by-grade buying notes, freight maths, supplier-tier pricing, and a worked landed-cost example, the sulfur (elemental) cornerstone hub covers the full sourcing chain.

For the structure and history of REACH, see the REACH glossary entry.

Need cross-jurisdiction compliance support on this substance? Run it through the REACH / TSCA / IECSC / AICIS / K-REACH checker, or send us the substance and the destination and we will quote FOB China and CIF / DDP landed including the regulatory work on the destination side.

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