Phosphorus (yellow / white / red) under K-REACH
P4 (white) / Pn (red) · 黄磷 / 白磷 / 红磷
Status: Registered. Phosphorus is registered under K-REACH. **Yellow / white phosphorus on Korea TCCA Toxic Chemicals list** (verify against the current TCCA Toxic Chemicals list at https://www.nics.go.kr/ and NICS toxic-chemical database before relying); red phosphorus typically not on TCCA. NOT on Korean Drug Management Act precursor list. NO active Korean AD/CVD case on Chinese-origin phosphorus currently (verify against https://www.kita.org/ or Korea Trade Commission filings before invoicing). Korea has limited domestic phosphorus production; structurally net-importer for Korean semiconductor electronic-grade red phosphorus + flame-retardant + matchstick / pyrotechnic / fertiliser sectors. KCFTA preferential zero-duty applies for Chinese-origin imports.
K-REACH treats yellow / white phosphorus as a **TCCA Toxic Chemicals scheduled substance** (TCCA Handling Permit at destination facility); red phosphorus typically not on TCCA. Korea net-importer with significant Chinese-origin import dependency for semiconductor electronic-grade red phosphorus. NO active Korean AD/CVD case. **Phosphorus distinguishing pattern across all 5 regimes**: Two industrially-relevant allotropes share CAS 7723-14-0; yellow / white phosphorus (P4 tetrahedral, pyrophoric, highly toxic) and red phosphorus (Pn polymeric, more stable, lower hazard) + production via electric-arc furnace from phosphate rock + silica + coke at ~1500 C yielding white phosphorus, optional thermal conversion to red + closes phosphorus chain upstream of H3PO4 batch 64 + DAP batch 30 + match / pyrotechnic / smoke-flare / semiconductor-doping (electronic-grade red phosphorus) plus PCl3 + PCl5 captive feedstock plus flame-retardant downstream chains + two-allotrope hazard profile (white Pyr. Sol. 1 + Acute Tox. 1 + Skin Corr. 1B + STOT RE 2 + Aquatic Acute 1; red Flam. Sol. 1 + Aquatic Acute 1) + IARC not classified + US OSHA PEL 0.1 mg/m3 + EPA RMP 100 lb white P + white P NOT on Cal Prop 65 (verify against OEHHA) + DEA List I 21 CFR 1310.02(a) red P + hypophosphorous acid + salts (meth precursors) + historical US AD on Chinese yellow P at access.trade.gov (verify current case-number + cash-deposit rate before invoicing) + EU previous AD Reg (EC) 2010/2003 historic + REACH Annex XVII matches / lighters restriction on white P + China dominates global production (Yunnan + Guizhou + Sichuan electric-arc clusters) + China Catalog of Hazardous Chemicals AND Highly Toxic Chemicals (yellow / white) + seasonal export-quota + export-licensing + Australian SUSMP Schedule 7 (yellow / white) + Korean TCCA Toxic Chemicals (yellow / white).
Listing and threshold
| Substance | Phosphorus (yellow / white / red) (CAS 7723-14-0), P4 (white) / Pn (red) |
|---|---|
| Regime | Korea Act on the Registration and Evaluation of Chemicals (Act No. 11789, "K-REACH" amended 2018) |
| Jurisdiction | Republic of Korea |
| Status | Registered |
| Tonnage threshold | K-REACH registration required for existing chemicals manufactured or imported >1 tonne/year (verified per Korean Ministry of Environment / NIER guidance, https://chemical.chemlinked.com/chempedia/k-reach; threshold for new substances was reduced from 0.1 t/y to 1 t/y effective 1 January 2025 per K-REACH 2025 amendment) |
Classifications under this regime
- Korean GHS classification: yellow / white phosphorus Pyr. Sol. 1 + Acute Tox. 1 + Skin Corr. 1B; red phosphorus Flam. Sol. 1
- **Yellow / white phosphorus on Korea TCCA Toxic Chemicals list** (verify against current TCCA list and NICS toxic-chemical database before relying)
- Red phosphorus typically not on TCCA Toxic Chemicals list (verify current status)
- NOT on Korean Drug Management Act precursor list
- Korean Customs Service (KCS) HS code: 280470
- IARC: Not classified
Restrictions and conditions of use
- **TCCA Toxic Chemicals Handling Permit required at destination facility for yellow / white phosphorus** (verify TCCA status against NICS database)
- KOSHA MSDS in Korean required at workplace (allotrope-specific hazard profile)
- NO active Korean AD/CVD case on Chinese phosphorus currently
- KCFTA preferential zero-duty applies (HS 280470)
Importer obligations
Korean importer of record must hold K-REACH registration AND TCCA Toxic Chemicals Handling Permit at destination facility for yellow / white phosphorus. Korea has limited domestic phosphorus production; structurally net-importer.
Required documents
- K-REACH registration number on Korean side
- Korean MSDS (allotrope-specific hazard profile)
- KCS declaration with HS 280470
- China-Korea FTA Form CO
- **TCCA Toxic Chemicals Handling Permit at destination facility for yellow / white phosphorus**
Common compliance traps
The pitfalls that have bitten importers on this lane in the past. None of these is theoretical.
- Korea has limited domestic phosphorus production; structurally net-importer
- KCFTA preferential zero-duty applies
- NO active Korean AD/CVD case
- **Yellow / white phosphorus on TCCA Toxic Chemicals list (TCCA Handling Permit at destination)**
- **Korean semiconductor electronic-grade red phosphorus demand for Samsung + SK Hynix + LG semiconductor doping**
Where to read next
For substance-level identifiers (formula, molecular weight, SMILES, InChIKey), GHS hazard profile, IMDG transport class, and full sourcing reference for phosphorus (yellow / white / red), see the CAS 7723-14-0 sourcing reference.
For grade-by-grade buying notes, freight maths, supplier-tier pricing, and a worked landed-cost example, the phosphorus (yellow / white / red) cornerstone hub covers the full sourcing chain.
For the structure and history of K-REACH, see the K-REACH glossary entry.
Need cross-jurisdiction compliance support on this substance? Run it through the REACH / TSCA / IECSC / AICIS / K-REACH checker, or send us the substance and the destination and we will quote FOB China and CIF / DDP landed including the regulatory work on the destination side.
Read next
Cross-jurisdiction profile and sourcing references
Regulatory
Phosphorus (yellow / white / red) under REACH
European Union listing status, classifications, importer obligations.
Regulatory
Phosphorus (yellow / white / red) under TSCA
United States of America listing status, classifications, importer obligations.
Regulatory
Phosphorus (yellow / white / red) under IECSC
People's Republic of China listing status, classifications, importer obligations.
Regulatory
Phosphorus (yellow / white / red) under AICIS
Australia listing status, classifications, importer obligations.
CAS
CAS 7723-14-0 sourcing reference
Identifiers, hazard profile, IMDG transport class, and supplier geography for Phosphorus (yellow / white / red).
Glossary
K-REACH, K-REACH
South Korean Act on the Registration and Evaluation of Chemicals, the Korean equivalent of EU REACH. Requires registration of substances manufactured in or imported into Korea above 1 tonne per year. Administered by the Ministry of Environment through NIER. Includes phase-in registration tiers, joint submission requirements, and a designated 'Only Representative' mechanism for non-Korean manufacturers.
Referenced in
5 pages across the Sourzi moat
This term shows up in 4 regulatory pages, 1 CAS profiles. Sample backlinks per content type below.
Regulatory (4)
Phosphorus (yellow / white / red) under REACH
European Union compliance profile for Phosphorus (yellow / white / red).
Phosphorus (yellow / white / red) under TSCA
United States of America compliance profile for Phosphorus (yellow / white / red).
Phosphorus (yellow / white / red) under IECSC
People's Republic of China compliance profile for Phosphorus (yellow / white / red).
Plus 1 more regulatory pages.
Free download
Free PDF: the same MSDS verification template the Sourzi team uses to cross-reference factory documents against TSCA, REACH, AICIS, and CDR before booking.