CAS 9002-88-4 · REACH · European Union

Polyethylene (PE; LDPE / LLDPE / HDPE / UHMWPE) under REACH

(C2H4)n · 聚乙烯

Status: Exempt. Polyethylene is **REACH-EXEMPT under Article 2(9) polymer exemption** (alongside PVC batch 10 + PP batch 47). **Distinguishing pattern: closes ethylene chain (largest petrochemical commodity globally, ethylene ~210 Mt/yr) + 4 grades (LDPE / LLDPE / HDPE / UHMWPE) + Article 2(9) polymer exemption + constituent monomer ethylene (CAS 74-85-1) IS REACH-registered + EU Polymer Strategy revision (2026-2027 timeline) high-priority polymer registration candidate + EU Single-Use Plastics Directive (Reg 2019/904) restricts certain PE plastic-bag + EPS + flexible packaging applications + EU PPWR (Packaging and Packaging Waste Regulation) Reg 2025/40 + Sinopec + CNPC + Hengli + Shenghong + Wanhua + ZRCC Chinese capacity dominance (NEW combined).** No GHS classification at industrial-grade. NOT SVHC. NOT Annex XIV.

PE is **REACH-exempt under Article 2(9) polymer exemption** (alongside PVC batch 10 + PP batch 47). **Closes ethylene chain** (largest petrochemical commodity globally). NOT SVHC. NO active EU AD case. NOT in CBAM Phase 1. **EU Polymer Strategy revision + EU PPWR Reg 2025/40 + EU Single-Use Plastics Directive Reg 2019/904** drive downstream packaging compliance. China dominates global PE capacity (~22%, ~25-30 Mt/yr but rapidly growing) led by Sinopec, CNPC, Hengli, Shenghong Petrochemical (Lianyungang Xuwei 16 Mt/yr world-largest single-site), Wanhua Chemical, Zhejiang Petrochemical / ZRCC.

Listing and threshold

Substance Polyethylene (PE; LDPE / LLDPE / HDPE / UHMWPE) (CAS 9002-88-4), (C2H4)n
Regime EU Regulation (EC) No 1907/2006: Registration, Evaluation, Authorisation and Restriction of Chemicals
Jurisdiction European Union (EU-27 plus EEA: Iceland, Liechtenstein, Norway)
Status Exempt
Tonnage threshold Article 2(9) polymer exemption: no REACH registration required for the polymer itself. Constituent monomer ethylene (CAS 74-85-1) IS REACH-registered

Classifications under this regime

  • Article 2(9) polymer exemption (constituent monomers separately registered)
  • NO harmonised CLP classification at industrial-grade level
  • IARC: not classified
  • EU Reg 10/2011 food-contact: PE permitted as plastic food-contact material; SML applies for monomer + additive migration
  • **EU Single-Use Plastics Directive (Reg (EU) 2019/904)** (verify the consolidated Directive text and effective date against EUR-Lex https://eur-lex.europa.eu/eli/dir/2019/904/oj before relying) + **EU PPWR (Packaging and Packaging Waste Regulation Reg (EU) 2025/40)** (verify the Regulation number, recycled-content targets, and effective dates against EUR-Lex https://eur-lex.europa.eu/ before relying) (effective phased 2025-2030)

Restrictions and conditions of use

  • Article 2(9) polymer exemption applies
  • NOT classified as SVHC
  • NOT subject to any Annex XVII restriction
  • NO active EU AD case on Chinese-origin PE currently
  • NOT in CBAM Phase 1 scope
  • **EU Polymer Strategy revision (2026-2027 timeline)** is candidate for polymer registration; PE high-priority
  • **EU PPWR (Reg 2025/40)** mandates 30% recycled-content for plastic packaging by 2030 + 40% by 2040

Importer obligations

Polymers REACH-exempt under Article 2(9). Major Chinese producers: Sinopec (Yangzi + Shanghai SECCO + Maoming + Yanshan), CNPC (Daqing + Karamay + Lanzhou), Hengli Petrochemical Dalian, Shenghong Petrochemical Lianyungang Xuwei, Wanhua Chemical Yantai, Zhejiang Petrochemical Zhoushan / ZRCC.

Required documents

  • Customs entry with HS code 39011000 (LDPE), 39012000 (HDPE), 39014000 (LLDPE), 39013000 (EVA)
  • EU Reg 10/2011 food-contact compliance documentation
  • **EU PPWR + Single-Use Plastics Directive compliance documentation** for downstream packaging applications

Common compliance traps

The pitfalls that have bitten importers on this lane in the past. None of these is theoretical.

  • **REACH-exempt under Article 2(9) polymer exemption** (alongside PVC batch 10 + PP batch 47)
  • **Closes ethylene chain** (largest petrochemical commodity globally, ethylene ~210 Mt/yr)
  • 4 grades: **LDPE** (low-density, film + flexible packaging), **LLDPE** (linear low-density, film + injection moulding), **HDPE** (high-density, rigid container + pipe + cable), **UHMWPE** (ultra-high-molecular-weight, technical applications)
  • Constituent monomer ethylene (CAS 74-85-1) IS REACH-registered separately
  • **EU Polymer Strategy revision (2026-2027 timeline)** is high-priority polymer registration candidate
  • **EU PPWR (Packaging and Packaging Waste Regulation Reg (EU) 2025/40)** (verify the Regulation number, recycled-content targets, and effective dates against EUR-Lex https://eur-lex.europa.eu/ before relying) mandates 30% recycled-content for plastic packaging by 2030 + 40% by 2040
  • **EU Single-Use Plastics Directive (Reg (EU) 2019/904)** (verify the consolidated Directive text and effective date against EUR-Lex https://eur-lex.europa.eu/eli/dir/2019/904/oj before relying) restricts certain PE products since July 2021
  • NO active EU AD case on Chinese PE currently
  • NOT in CBAM Phase 1
  • Major Chinese producers: Sinopec, CNPC, Hengli, **Shenghong Petrochemical Lianyungang Xuwei (a leading single-site integrated petrochemical complex; verify the most recent commissioning date and combined capacity Mt/yr against Shenghong Petrochemical investor disclosures and the Lianyungang Xuwei park public documents before quoting world-largest rank or a specific Mt/yr figure; sister batch to Lianyungang Xuwei park 50 atlas)**, Wanhua Chemical Yantai, Zhejiang Petrochemical Zhoushan / ZRCC. China dominates global PE capacity (~22%, ~25-30 Mt/yr but rapidly growing)
  • Production routes: gas-phase (UNIPOL + INEOS + Lupotech), solution (Sclairtech), high-pressure tubular reactor (LDPE) + autoclave (LDPE specialty)
  • End-use mix: film + flexible packaging (~50%, dominant LDPE + LLDPE end-use), rigid container + bottle (~20%, HDPE), pipe + cable (~10%, HDPE), other (~20%)

Where to read next

For substance-level identifiers (formula, molecular weight, SMILES, InChIKey), GHS hazard profile, IMDG transport class, and full sourcing reference for polyethylene (pe; ldpe / lldpe / hdpe / uhmwpe), see the CAS 9002-88-4 sourcing reference.

For grade-by-grade buying notes, freight maths, supplier-tier pricing, and a worked landed-cost example, the polyethylene (pe; ldpe / lldpe / hdpe / uhmwpe) cornerstone hub covers the full sourcing chain.

For the structure and history of REACH, see the REACH glossary entry.

Need cross-jurisdiction compliance support on this substance? Run it through the REACH / TSCA / IECSC / AICIS / K-REACH checker, or send us the substance and the destination and we will quote FOB China and CIF / DDP landed including the regulatory work on the destination side.

Free download

Free PDF: the same MSDS verification template the Sourzi team uses to cross-reference factory documents against TSCA, REACH, AICIS, and CDR before booking.